As Gerardo said, you should edit /etc/lvm/lvm.conf.
1.) In the "devices {" group near the beginning of the lvm.conf file, there is a line:
preferred_names = [ ]
Comment out the default line, and write in a custom filter instead. The result should look like this:
# preferred_names = [ ]
preferred_names = [ "^/dev/emcpower", "^/dev/mapper/", "^/dev/mapper/mpath", "/dev/[hs]d" ]
This will cause the LVM to prefer the EMC devices if it sees more than one PV with the same PV identifier (= the same LUN through different paths).
2.) Gerardo's filter line can achieve the same effect, but it assumes you are running on a Proliant system and have your vg00 on a SmartArray controller.
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