No, dump volumes should never be mirrored (unless they also serve as swap volumes and then they should always be mirrored).
If you want to configure separate dump and swap areas (and I 'll take the simplistic view that you are mirroring on identical physical disks) then all the LVOL's in /dev/vg00 should be mirrored except what ever LVOL's you create to be the dump area's. For that, if for example, you wanted 5GiB total of dump space, you would create 2 2.5GiB LVOL's (with different names and allocate each one from separate PV's). You then run lnlvboot -d twice and specify these dump LVOL's.
If it ain't broke, I can fix that.