Hi Roger,
I agree with Clay that you should have both mirrors complete before reducing the original.
Yes you can create both mirrors at the same time
lvextend -m 2 /dev/vg00/lvolx /dev/rdsk/disk1 /dev/rdsk/disk2
One thing to consider is that even though you'll be mirrored - you'll still have a SPOF in the controller. Is there a reason you cannot leave a mirror copy on the 12H?
I always prefer to have my VG00 mirrors on diff paths for this reason.
Rgds,
Jeff
PERSEVERANCE -- Remember, whatever does not kill you only makes you stronger!